Study of structural parameters on the adsorption selectivity of a molecularly imprinted polymer |
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| Authors: | Dong Lei Liu Xue Yan Du Zhen Liu |
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| Affiliation: | 1. State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology, Lanzhou, China;2. Department of Physics and Engineering, Frostburg State University, Frostburg, Maryland, United States |
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| Abstract: | This work was focused on the influence of match degree of structure parameters i.e. molecular size, volume and polarity (denoted as Rd, Vd and Pd) between imprinted cavities in Qu-MIP and Xn on the adsorption selectivity. The results presented that the influence of Rd on the adsorption selectivity was the largest and the most regular, while the influence of Pd was the smallest and the most irregular. Besides, the influence degree of Vd was decreased in general with the increase of Rd. However, as Rd was in the threshold of [0.99, 1.02], Vd would rise to the major influence factor. Furthermore, utilizing data obtained from experiment, the influence authority of Rd, Vd and Pd on the adsorption selectivity was calculated theoretically through multiple linear regression and principal component analysis of IBM SPSS Statistics 20, and results showed the authority order was Rd, Vd and Pd at any circumstance despite the value was different, which was in accordance with the result we directly inducted from the experiment. |
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| Keywords: | molecularly imprinted polymer molecular size molecular volume molecular polarity adsorption selectivity |
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