Oxo-tricyano complexes of molybdenum(IV) and tungsten(IV) with bidentate Schiff bases |
| |
Authors: | Beata Burda John Burgess Simon A. Parsons Alina Samotus Janusz Szklarzewicz |
| |
Affiliation: | (1) Department of Chemistry, Leicester University, University Road, LE1 7RH Leicester, UK;(2) Faculty of Chemistry, Jagiellonian University, R. Ingardena 3, 30-060 Kraków, Poland |
| |
Abstract: | Summary The reaction of [M(CN)4O(OH2)]2– (M = Mo or W) with 2-acetylpyridine and methyl-or butyl-amine in a water-MeOH mixture gave [M(CN)3O(L-L)]- (L-L= Schiff base ligand), isolated as [AsPh4]+ salts. The complexes have been characterized by elemental analysis, and electronic, i.r. and1H-n.m.r. spectroscopy. The Schiff base ligands complex in a bidentate manner through the two nitrogen atoms giving mixed-ligand compounds similarly to 2,2-bipyridyl or 1,10-phenanthroline.On leave from the Faculty of Chemistry, Jagiellonian University, Kraków. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|