Nuclear magnetic spin-rotational relaxation times for symmetric molecules |
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Authors: | James McConnell |
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Affiliation: | Dublin Institute for Advanced Studies, Dublin 4, Ireland |
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Abstract: | It is shown that the problem of calculating times related to nuclear magnetic spin-rotational interactions may be solved for the symmetric rotator model of a molecule by employing the method already proposed in a general manner for asymmetric molecules that undergo rotational thermal motion. Expressions are derived for the spin-rotational correlation time and for the contributions arising from spin-rotational interactions to the longitudinal and transverse relaxation times. |
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