| Molecular Structure of Organolanthanide Complex ［（η~5－CH_3C_5H_4）_2Tb（μ－Cl）（THF）］_2 |
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| 作者姓名： | WU Zhong-Zhi HUANG Zu-En CAI Rui-Fang |
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| 作者单位： | WU Zhong-Zhi; HUANG Zu-En; CAI Rui-Fang(Department of Chemistry，Fudan University Shanghai 200433)ZHOU Xi-Geng; XU Zheng; YOU Xiao-Zeng(State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing 210093)HUANG Xiao-Ying(State Key Laboratory |
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| 摘 要： | ＭｏｌｅｃｕｌａｒＳｔｒｕｃｔｕｒｅｏｆＯｒｇａｎｏｌａｎｔｈａｎｉｄｅＣｏｍｐｌｅｘ［（η~５－ＣＨ_３Ｃ_５Ｈ_４）_２Ｔｂ（μ－Ｃｌ）（ＴＨＦ）］_２ＷＵＺｈｏｎｇ－Ｚｈｉ；ＨＵＡＮＧＺｕ－Ｅｎ；ＣＡＩＲｕｉ－Ｆａｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅ...
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Molecular Structure of Organolanthanide Complex [(η￣5-CH_3C_5H_4)_2Tb(μ-Cl)(THF)]_2 |
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| WU Zhong-Zhi, HUANG Zu-En, CAI Rui-Fang.Molecular Structure of Organolanthanide Complex [(η￣5-CH_3C_5H_4)_2Tb(μ-Cl)(THF)]_2[J].Chinese Journal of Structural Chemistry,1996(5). |
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| Authors: | WU Zhong-Zhi HUANG Zu-En CAI Rui-Fang |
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| Abstract: | The complex (η5-CH3C5H4)2Tb(μ-Cl) (THF)]2, has been studied by X-ray crystallography. The crystal is orthorhombic , space group Phcn with a= 20.414(2),b=9. 548(1),c=16.390(6)A.V=3194.9(6) A3, Mr=849.46,Z=4,Dc=1.77 g/cm3, F(000)=1664,μ=46.37 cm-1.The Tb3+ ion is coordinated by two CH3C5H4 groups, two chloride ions and one oxygen atom from tetrahydrofuran to form a distorted trigonal bipyramidal geometry. Two bridging Tb-Cl bond lengths are 2. 716(2) and 2.790(2)A,respectively.The Tb-O (THF) and average Tb-C(CH3C5H4) bond lengths are 2.559(6) and 2.670(4)A,respectively. |
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| Keywords: | lanthanide terbium methylcyclopentadienyl crystal structure |
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