Self-assembly of Pt(II) spherical complexes via temporary labilization of the metal-ligand association in 2,2,2-trifluoroethanol |
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| Authors: | Fujita Daishi Takahashi Asana Sato Sota Fujita Makoto |
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| Institution: | Department of Applied Chemistry, School of Engineering, The University of Tokyo, and CREST, Japan Science and Technology Agency, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. |
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| Abstract: | Thermodynamically controlled platinum(II) spherical complexes were synthesized via temporary labilization of inert Pt(II)-pyridine bonds by the addition of the strong hydrogen-bond donor 2,2,2-trifluoroethanol (TFE), which weakens the pyridine-metal interaction. The platinum complex was stably trapped after removal of TFE and showed higher acid durability than its palladium counterpart. |
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