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Steroid compounds from the Pacific starfish Lysastrosoma anthosticta
Authors:Levina  E V  Andriyashchenko  P V  Kalinovskii  A I  Stonik  V A
Institution:(1) Pacific Institute of Bioorganic Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022 Vladivostok, Russian Federation
Abstract:Two new steroid compounds, 3beta,6agr-dihydroxy-5agr-cholesta-9(11),24-dien-23-one 3-sulfate and 3beta,6agr-dihydroxy-5agr-cholest-9(11)-en-23-one 3-sulfate, were isolated from the Pacific starfish Lysastrosoma anthosticta as the corresponding sodium salts and identified. Two previously known glycosides of 24(S)-5agr-cholestane-3beta,6agr,8,15beta,24-pentol were also isolated and identified as sodium 24-O-beta-d-glucopyranoside 6"-sulfate (pycnopodioside C) and sodium 24-O-beta-d-xylopyranoside 4"-sulfate (luridoside A).
Keywords:starfish  polyhydroxysteroids  glycosides  aglycons  Lysastrosoma anthosticta  NMR spectra
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