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Laser-induced down-conversion parameters of singly and doubly doped ZnS phosphors
Authors:H S Bhatti  Rajesh Sharma  N K Verma
Institution:(1) Department of Physics, Punjabi University, 147 002 Patiala, India;(2) Institute of Engineering and Emerging Technologies, Baddi, Dist, 173 205 Solan, India;(3) SPMS, Thapar Institute of Engineering and Technology, 147 004 Patiala, India
Abstract:Singly and doubly doped ZnS phosphors have been synthesized using flux method. Laser-induced photoluminescence has been observed in ZnS-doped phosphors when these were excited by the pulsed UV N2 laser radiation. Due to down-conversion phenomenon, fast phosphorescence emission in the visible region is recorded in milliseconds time domain for ZnS:Mn while in the case of ZnS:Mn:killer (Fe, Co and Ni) the lifetime reduces to microseconds time domain. Experimentally observed luminescent emission parameters of excited states such as, lifetimes, trap-depth values and decay constants have been reported here at room temperature. The high efficiency and fast recombination times observed in doped ZnS phosphors make these materials very attractive for optoelectronic applications.
Keywords:UV laser excitation  quencher impurities  excited state lifetimes  laserinduced photoluminescence
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