| 对硫磷分子印迹聚合物制备及其在水质检测中的应用 |
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| 引用本文： | 刘静,曾兴宇,刘小骐,王意,赵戌龙,冯晏辉,潘献辉.对硫磷分子印迹聚合物制备及其在水质检测中的应用[J].分析试验室,2012(9):81-84. |
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| 作者姓名： | 刘静 曾兴宇 刘小骐 王意 赵戌龙 冯晏辉 潘献辉 |
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| 作者单位： | 国家海洋局天津海水淡化与综合利用研究所 |
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| 基金项目： | 国家海洋局业务化项目(1511112000005);中央级公益性科研院所基本科研业务费专项资金项目(K-JBYWF-2010-G16)资助 |
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| 摘 要： | 为了有效的分离富集水样中有机磷农药,以对硫磷为模板、三羟甲基丙烷三丙烯酸酯为交联剂,采用紫外聚合方法制备了对硫磷分子印迹聚合物(MIP)。利用紫外光谱、红外光谱研究了对硫磷与不同功能单体间作用力及印迹聚合物的结合位点。利用该MIP,建立MIP-固相萃取-气相色谱法测定水中痕量对硫磷,方法的检出限(3S/N)为0.48μg/L,加标回收率为86.2%～115.7%,相对标准偏差(n=6)为3.0%～6.6%。
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| 关 键 词： | 分子印迹聚合物 光聚合 对硫磷 固相萃取-气相色谱 水 |
Preparation of parathion imprinted polymer and its application for the determination of parathion in water |
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| LIU Jing,ZENG Xing-yu,LIU Xiao-qi,WANG Yi,ZHAO Xu-long,FENG Yan-hui and PAN Xian-hui.Preparation of parathion imprinted polymer and its application for the determination of parathion in water[J].Chinese Journal of Analysis Laboratory,2012(9):81-84. |
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| Authors: | LIU Jing ZENG Xing-yu LIU Xiao-qi WANG Yi ZHAO Xu-long FENG Yan-hui and PAN Xian-hui |
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| Institution: | (Institute of Seawater Desalination and Multipurpose Utilization,State Oceanic Administration,Tianjin 300192) |
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| Abstract: | In order to separate and concentrate the parathion in water efficiently,the molecularly imprinted polymer(MIP) was synthesized by photo-polymerization with parathion as the template molecule and TMPTA as a crosslinking agent.According to the UV and IR spectra,the interaction between parathion and functional monomers were studied and the MIP was evaluated.The above prepared MIP was used to extract parathion in water samples with SPE-GC,the detection limit(3S/N) was 0.48 μg/L.Recoveries were 86.2%～115.7 % and relative standard deviations(n=6) were 3.0%～6.6%. |
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| Keywords: | Molecularly imprinted polymer Photo-polymerization Parathion SPE-GC Water |
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