Adsorption of a cationic porphyrin onto mesoporous silicas |
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Authors: | Atsuko Yoshida Norishige Kakegawa Makoto Ogawa |
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Affiliation: | 1. Department of Earth sciences and Graduate School of Science and Engineering, Waseda University, Nishiwaseda 1-6-1, 169-8050, Shinjuku-ku, Tokyo, Japan
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Abstract: | The adsorption of a cationic porphyrin, tetrakis-(N-methyl-4-pyridiniumyl)porphine, into mesoporous silicas from solution of tetrakis-(N-methyl-4-pyridiniumyl)porphine p-toluene sulfonate was investigated. Irrespective of the pore size (2.4, 3.5 and 4.2 nm), the cationic porphyrin was adsorbed effectively onto mesoporous silicas to give brown-colored powders. Depending on the amounts adsorbed, which correlate with the average intermolecular distance, the porphines tend to aggregate (dimer). |
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