Reactions of organocobaloximes with aryldisulfonyl chlorides |
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| Authors: | B.D. Gupta V. Vijaikanth |
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| Affiliation: | Department of chemistry, Indian Institute of Technology, Kanpur 208016, India |
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| Abstract: | Photochemical reactions of benzyl, heteroaromaticmethyl and allylcobaloximes with aryldisulfonyl chlorides yield symmetrical disulfones. Allyl cobaloximes yield allyldisulfones as the major product whereas bibenzyl is the major product in benzylcobaloximes. A time dependent 1H NMR studies show that bibenzyl is formed from O-benzyldimethylglyoxime - a predominant product in the initial stage of the reaction. |
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| Keywords: | Organocobaloximes Disulfonyl chlorides SH2 reactions Disulfone Bibenzyl-O-benzyldimethylglyoxime 1H NMR studies |
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