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Selective formation of trans and cis(CH3CN) isomers of [Ru(bpy)(CO)2(CH3CN)2] (bpy=2,2-bipyridine) from [Ru(CO)2(CH3CN)3]2(PF6)2 using an electrochemical oxidation step |
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| Authors: | Garth Cripps Sylvie Chardon-Noblat Alain Deronzier |
| Institution: | a Laboratoire d’Electrochimie Organique et de Photochimie Rédox, UMR CNRS 5630, Institut de Chimie Moléculaire de Grenoble FR 2607, Université Joseph Fourier, Grenoble 1, BP 53, 38041 Grenoble cedex 9, France b Department of Chemistry, University of Natal, Private Bag X01, Scottsville, Pietermaritzburg 3209, South Africa |
| Abstract: | The selective in situ synthesis of trans and cis(CH3CN)-Ru(bpy)(CO)2 (CH3CN)2]2+ isomers from the same Ru(CO)2 (CH3CN)3]22+ dimer precursor but using either an electrochemical-chemical or chemical-electrochemical process is described. |
| Keywords: | Ruthenium complexes Carbonyl compounds Electrosynthesis Electrochemical oxidation |
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