A multinuclear NMR study in the solid state and in solution of thallium(I) tris-(pyrazol-1-yl)borates (thallium scorpionates) |
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Authors: | Rosa M Claramunt,Dionisia Sanz,José Elguero |
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Abstract: | The 1H, 13C and 15N NMR spectroscopic properties of six thallium tris-(pyrazol-1-yl)borates, including a tetrakis derivative, were determined. The results in solution were necessary to understand those, more complicated, in the solid state. A collection of 205Tl-15N and 205Tl-13C couplings was measured in the latter state. Among those, a very large coupling constant (between 194 and 282 Hz) has been measured on the carbon at the position 4 of the pyrazole ring in several compounds and particularly for the cyclobutyl derivative [Tl(TpCbu)]. It has been assigned to a direct interaction of the 4-C-H ? Tl type and related to the X-ray structures, when available. |
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Keywords: | Pyrazolylborates Thallium 1H NMR 13C NMR 15N NMR CPMAS |
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