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The chemistry of (1-azabuta-1,3-diene)tricarbonyliron(0) complexes
Authors:Timothy N Danks  Gabriele Wagner
Institution:a Chemistry Division, SBMS, University of Surrey, Guildford, Surrey GU2 7XH, UK
b The Oratory School, Woodcote, Reading, Berkshire RG8 0PJ, UK
Abstract:In this review, an overview of synthetic and structural aspects of 1-azabuta-1,3-diene complexes of iron is given and the reactivity of these complexes is discussed with regard to inorganic, organometallic, organic and stereochemical aspects of their chemistry. Their application in the synthesis of organic and organometallic target compounds, or as transfer reagents of the tricarbonlyiron(0) moiety is demonstrated.
Keywords:Azabutadiene  Tricarbonyliron(0)  Synthesis  Structure  Reactivity
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