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Zn2+ and EDTA Cooperative Switchable Nanofluidic Diode Based on Asymmetric Modification of Single Nanochannel
Authors:Yao Sun  Fan Zhang  Zhongyue Sun  Miaomiao Song  Demei Tian  Prof Haibing Li
Institution:Department Key Laboratory of Pesticide and Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, P.R. China
Abstract:Design and fabrication of smart switchable nanofluidic diodes remains a challenge in the life and materials sciences. Here, we present the first example of a novel Zn2+/EDTA switchable nanofluidic diode system based on the control of one‐side of the modified hourglass‐shaped nanochannel with salicylaldehyde Schiff base (SASB). The nanofluidic diode can be turned on in the response of Zn2+ and turned off in response to EDTA solution with good reversibility and recyclability.
Keywords:biomimetic synthesis  nanochannels  nanofluidic diodes  nanostructures  Schiff bases
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