Aerobic oxidation under visible light irradiation of a fluorescent lamp with a combination of carbon tetrabromide and triphenyl phosphine |
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| Authors: | Taichi Sugai Akichika Itoh |
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| Institution: | aGifu Pharmaceutical University 5-6-1, Mitahora-higashi, Gifu 502-8585, Japan |
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| Abstract: | A combination of CBr4–Ph3P, a non-metal method, enables us to carry out aerobic photo-oxidation of alcohols and aromatic methyl groups to the corresponding carboxylic acids under irradiation of vis from a general-purpose fluorescent lamp. Aliphatic primary- and secondary alcohols, benzyl alcohols, and methyl groups at the aromatic nucleus generally afforded the carboxylic acids directly in good to high yield. |
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| Keywords: | Aerobic oxidation Carbon tetrabromide Fluorescent lamp Triphenylphosphine Visible light |
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