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Synthesis and mesomorphic properties of fluoro and isothiocyanato biphenyl tolane liquid crystals
Authors:Yung‐Ming Liao  Narayanasamy Janarthanan  Sebastian Gauza  Shin‐Tson Wu
Institution:1. Department of Applied Chemistry , National Chiao Tung University , Hsinchu 30010, Taiwan, R.O.C;2. College of Optics and Photonics , University of Central Florida , Orlando, FL 32816
Abstract:Four series of high birefringence biphenyl tolane liquid crystals having a terminal isothiocyanato or fluoro group were synthesized; their mesomorphic properties were studied by optical polarizing microscopy and DSC. These biphenyl tolane compounds exhibit reasonably low melting points and high birefringence of 0.37–0.49. By using these compounds a eutectic mixture was formulated exhibiting a wide nematic range, high figure‐of‐merit and low viscosity.
Keywords:nematic liquid crystals  flexoelectric  hybrid alignment  ionic conductivity
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