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Synthesis and mesomorphic properties of chiral liquid crystal dimers derived from azobenzene and substituted naphthol |
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| Authors: | Guan-Yeow Yeap Subramanian Balamurugan Samikannu Rakesh |
| Affiliation: | 1. Liquid Crystal Research Laboratory, School of Chemical Sciences , Universiti Sains Malaysia , Penang , Malaysia gyyeap@usm.my;3. Liquid Crystal Research Laboratory, School of Chemical Sciences , Universiti Sains Malaysia , Penang , Malaysia;4. Department of Chemistry , Anna University , Chennai , India |
| Abstract: | Symmetrical liquid crystal dimers bis{2-alkyl-(S)-(+)-2-(6-[4-4′-decyloxyphenylazo)-benzoyloxy]-2-naphthyl)propinate} have conveniently been designed, synthesised and their mesomorphic properties were investigated. These dimers possess two identical mesogenic units with each of them attached to the terminal end of a flexible spacer (–C n H2n ; where n = 6–10). The respective mesogenic unit was made up from a naphthyl ring attached to the alkyloxylated azobenzene via the ester (COO–) bond. The chiral moiety attached to the 6-position of the naphthyl ring possesses a terminal carboxylic group COO– which linked up the mesogenic unit and the spacer. The thermal and optical properties for the ultimate compounds at different temperature were studied explicitly with the aids of differential scanning calorimetry and polarising optical microscopy. All dimers exhibit unambiguously the monotropic nematic and smectic A phases. The homeotropic alignment of the molecules within the anisotropic region was further confirmed through the application of homogeneously treated cell. |
| Keywords: | symmetrical dimer mesogenic units chiral moiety homeotropic alignment |