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Synthesis,mesogenic and dielectric properties of fluorosubstituted isothiocyanatoterphenyls
Authors:?ukasz Szczuciński  Stanis?aw Urban  Katarzyna Garbat  Marek Filipowicz  Jerzy Dziaduszek
Institution:1. Institute of Chemistry, Military University of Technology, Warsaw, Poland;2. Institute of Physics, Jagiellonian University, Krakow, Poland
Abstract:The synthesis, mesomorphic and physical properties of 14 homologous series of laterally fluorinated 4?-alkyl-4-isothiocyanatoterphenyls were described. Influence of the number of fluorine atoms and their position in the terphenyl core on the phase transition temperatures, nematic range, dielectric and optic anisotropy as well as bulk viscosity were discussed. The compounds with the most optimal properties for formulation of nematic mixtures were selected, and mixture examples with low viscosity and medium or high birefringence were presented.
Keywords:liquid crystal  nematic compound  synthesis of isothiocyanatoterphenyl  high birefringence  dielectric anisotropy  viscosity  liquid crystal mixture
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