Effect of molecular structure on mesomorphism XX. Unsymmetrical dimeric mesogens |
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| Authors: | Anselm C. Griffin Shailaja R. Vaidya |
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| Affiliation: | 1. Departments of Chemistry and Polymer Science , University of Southern Mississippi , Hattiesburg, Mississippi, 39406, U.S.A.;2. Departments of Chemistry and Polymer Science , University of Southern Mississippi , Hattiesburg, Mississippi, 39406, U.S.A.;3. Departments of Chemistry , University of Southern Mississippi , Hattiesburg, Mississippi, 39406, U.S.A.;4. Polymer Products Department, E. I. duPont de Nemours &5. Company , Parkersburg, West Virginia, 26102, U.S.A. |
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| Abstract: | Abstract A series of unsymmetrical dimeric mesogens was prepared, members of which were composed of a 4′-pentyloxybiphenyl-4-carboxyl core and a 4′-substituted-benzylidene-4-oxyaniline core joined via an alklyene spacer. The structural variants were cyano, nitro and trifluoromethyl. Comparison of mesophase behaviour of the unsymmetrical dimers with that of corresponding monomeric ‘halves’ and also with that of corresponding symmetrical dimers indicated a tendency for the unsymmetrical dimers to form smectic phases although not as highly ordered as those of some of the monomers corresponding to a relevant core group. |
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