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Orientation control over bent-core smectic liquid crystal phases
Authors:Hanim Kim  Yun Ho Kim  Sunhee Lee  David M. Walba  Noel A. Clark  Sang Bok Lee
Affiliation:1. Graduate School of Nanoscience and Technology (WCU), KAIST, Daejeon, Republic of Korea;2. Advanced Functional Materials Research Group, Korea Research Institute of Chemical Technology, Daejeon, Republic of Korea;3. Department of Chemistry and Liquid Crystal Materials Research Center, University of Colorado, Boulder, CO, USA;4. Department of Physics and Liquid Crystal Materials Research Center, University of Colorado, Boulder, CO, USA;5. Department of Chemistry and Biochemistry, University of Maryland, College Park, MD, USA
Abstract:Bent-core smectic liquid crystal (LC) phases (B phases) have been widely studied since their unusual polar and chiral properties were discovered in the 1990s. Relatively few studies have examined the mechanisms by which the orientation of the B phase may be controlled to produce the type of macroscopic domain that is essential for organic semiconductor, optical device and patterning applications. This review is intended to cover recent progress towards controlling the B phases upon layering, including anisotropic treatment methods and topographical confinement methods. Finally, this review closes with a discussion of B smectic phases that have been fabricated for use in certain applications.
Keywords:bent-core molecules  liquid crystal phases  orientation control  external fields  topographic confinement
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