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Study on selective reflection properties of chiral nematic liquid crystalline composites with a non‐uniform pitch distribution
Authors:Wei Huang  Zhenyu Bian  Kexuan Li  Jiumei Xiao  Hui Cao
Institution:1. Department of Materials Physics and Chemistry , School of Materials Science and Engineering , University of Science and Technology Beijing , Beijing 100083, People's Republic of China;2. Department of Materials Physics and Chemistry , School of Materials Science and Engineering , University of Science and Technology Beijing , Beijing 100083, People's Republic of China;3. College of Applied Science , University of Science and Technology Beijing , Beijing 100083, People's Republic of China
Abstract:The preparation is reported of particles of photopolymerisable monomer/chiral dopant composites with a crystalline (Cr)‐chiral nematic (N*) phase transition. By mixing particles with different pitches of the N* phase in the Cr phase and crosslinking the liquid crystal (LC) monomer molecules by photopolymerisation in the planarly oriented N* phase, an N*‐LC composite film with a non‐uniform pitch distribution was obtained. Experimental results show that the bandwidth of the reflection spectrum and the location of reflection band of the composite films can be controlled accurately by controlling the pitch lengths of the N* phase of the particles. Effects of polymerisation temperature and UV intensity on the non‐uniform pitch distribution of N*‐LC composite films were investigated.
Keywords:non‐uniform pitch distribution  chiral nematic composite  photopolymerisation  selective reflection
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