Complexation of Amino Acid Methylesters and Amino Alcohols by 18-Crown-6 and Benzo-18-crown-6 in Methanol |
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| Authors: | H-J Buschmann E Schollmeyer L Mutihac |
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| Institution: | (1) Deutsches Textilforschungszentrum Nord-West E.V., Adlerstrasse 1, D-47798 Krefeld, Germany;(2) Department of Analytical Chemistry, Faculty of Chemistry, University of Bucharest, 4–12 Regina Elisabeta Blvd., Bucharest, 70346, Romania |
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| Abstract: | The complexation of protonated amino acid methylesters and amino alcohols bythe ligands 18-crown-6 (18C6) and benzo-18-crown-6 (B18C6) has been studiedin methanol using calorimetric titrations. No influence of the anions upon thestability constants and thermodynamic data for the reaction of protonated aminoacid methylesters with both ligands has been noticed, which indicates the completedissociation of the salts employed. A similar effect has been observed for thecomplexation of protonated and unprotonated amino alcohols with 18C6 andB18C6. The values obtained of the reaction enthalpies for the complexation ofprotonated amino acid methylesters with 18C6 are larger than those correspondingto the complexation with B18C6. The results demonstrate that the complex formationof unprotonated amino alcohols is favored by entropic contributions, while thecomplexation of protonated amino alcohols is favored by enthalpic contributionswith both ligands. The influence of various substituents on the complexation behaviorof amino acid and amino alcohol has also been investigated. |
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| Keywords: | amino acid methylesters amino alcohols calorimetry complexes crown ethers molecular recognition thermodynamics |
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