Palladium(II) and platinum(II) chloride and bromide complexes with some 2-methylpyridyl- or methylquinolyl-benzimidazole,benzoxazole, or benzthiazole |
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Authors: | Giovanni Coni Marcella Massacesi Gustavo Ponticelli Giovanna Puggioni Costantino Putzolu |
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Institution: | (1) Istituto di Chimica Generale, Inorganica ed Analitica, Università di Cagliari, Via Ospedale 72, 09124 Cagliari, Italy |
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Abstract: | Summary Palladium(II) and platinum(II) complexes MLX2], where L=2-(4 -methyl-2 -pyridyl)benzimidazole (mpbi), 2-(4 -methyl-2 -pyridyl)benzoxazole (mpbo), 2-(4 -methyl-2 -quinolyl)benzoxazole (mpbo), 2-(4 -methyl-8 -quinolyl)benzoxazole (mq'bo), X=Cl. Br, together with M(mqbo)2Br2 and Pt2(mpbt)Cl4, where mpbt=2-(4 -methyl-2 -pyridyl)benzthiazole, have been synthesized and characterized by conductivity and magnetic measurements as well as by i.r. and electronic spectra. The ligands are bidentate chelates through the pyridine or quinoline and isoxazole or imidazole nitrogen atoms. The MLX2] derivatives arecis, square planar. |
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