| Abstract: | Organoantimony Compounds. V. The Reactivity of Phenyl Stibine C6H5SbH2, synthesized by the reduction of C6H5SbCl2 with LiBH4, reacts with LiR under certain conditions forming (C6H5Sb)n and H2 or give by a partially elimination of H2 stibides with a different structure. The latter react with alkyl and aryl halides forming tert. stibines which may be characterized as the corresponding dibromides. The preparation of C6H5SbNa2 and its reaction with C2H5Br, Cl(CH2)4Cl and C6H5(Cl)C?N? N?C(Cl)C6H5 are described. |
