Dynamic ligation at the first amine-coordinated iron hydrogenase active site mimic |
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| Authors: | Schwartz Lennart Ekström Jesper Lomoth Reiner Ott Sascha |
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| Affiliation: | Department of Photochemistry and Molecular Science, Uppsala University, Box 523, 75120, Uppsala, Sweden. |
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| Abstract: | The first model of the iron hydrogenase active site has been prepared in which an amine ligand is loosely coordinated to an Fe(i) centre, and can be replaced by a solvent molecule; irrespective of the ligand set, the one electron reduction of both complexes is chemically reversible and is shown to proceed through the same species which features a bridging CO ligand. |
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