| [Na(DB24C8)]3[α-AsMo12O40]·9H2O超分子的合成与晶体结构 |
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| 引用本文： | 顾新波,鲁晓明,萨如拉,邓元,叶朝辉.[Na(DB24C8)]3[α-AsMo12O40]·9H2O超分子的合成与晶体结构[J].无机化学学报,2007,23(4):669-672. |
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| 作者姓名： | 顾新波 鲁晓明 萨如拉 邓元 叶朝辉 |
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| 作者单位： | 1. 首都师范大学化学系,北京,100037
2. 中国科学院武汉物理与数学研究所,武汉,430071 |
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| 摘 要： | The complex of Na(DB24C8)]3α-AsMo12O40]·9H2O was synthesized by hydrothermal techniques and cha-racterized by IR and X-ray diffraction analysis. Single crystal X-ray diffraction indicate that this complex is belong to monoclinic, space group P21/n with cell dimension: a=1.480 3(7) nm, b=2.692 7(3) nm, c=3.046 6(4) nm, α=90.00°, β=95.4120(10)°, γ=90.00°. V=12.090 28 nm3, Z=4, F(000)=6 440.0, R=0.050 9, wR2=0.113 5. The crown ethers just coordinate with Na+ and have no direct interaction with the polyoxometalate, because the crown ethers have a contorted configuration. CCDC: 626686.
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| 关 键 词： | 水热合成 钼砷杂多酸 冠醚 晶体结构 |
| 文章编号： | 1001-4861(2007)04-0669-04 |
| 修稿时间： | 2006-03-20 |
Syntheses and Crystal Structure of[Na(DB24C8)]3[α-AsMo12O40]·9H2O |
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| GU Xin-Bo,LU Xiao-Ming,Sarul,DENG Yuan and YE Chao-Hui.Syntheses and Crystal Structure of[Na(DB24C8)]3[α-AsMo12O40]·9H2O[J].Chinese Journal of Inorganic Chemistry,2007,23(4):669-672. |
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| Authors: | GU Xin-Bo LU Xiao-Ming Sarul DENG Yuan and YE Chao-Hui |
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| Institution: | Department of Chemistry, Capital Normal University, Beijing 100037,Department of Chemistry, Capital Normal University, Beijing 100037,Department of Chemistry, Capital Normal University, Beijing 100037,Department of Chemistry, Capital Normal University, Beijing 100037 and Wuhan Institute of Physics and Mathematics, Wuhan 430071 |
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| Abstract: | |
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| Keywords: | hydrothermal technique molybdoarsenate crown ether crystal structure |
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