| Samarium(II) Diiodide Induced Polarity Inversion of π-Allyl Palladium Complexes: The Formation of Allylic Selenides |
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| 作者姓名： | Xin Jian ZHAO Hua Rong ZHAO* Xian HUANG* Zhejiang Institute of Calibaration and Testing for Technical Superision Hangzhou |
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| 作者单位： | Xin Jian ZHAO1，Hua Rong ZHAO2*，Xian HUANG2* 1Zhejiang Institute of Calibaration and Testing for Technical Superision，Hangzhou 310013 2Department of Chemistry，Zhejiang University，Hangzhou 310027 |
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| 摘 要： | As a versatile one-electron transfer reducing and coupling agent, samarium diiodide has been extensively used in organic synthesis in last decade. It has been reported that electrophilic p-allyl palladium complexes could undergo polarity inversion to nucleophilic species with the aid of SmI2, and could trap some electrophiles1. It is well known that allylic selenides are rather important intermediates in organic synthesis. They have been recognized as useful synthons of allylic anion stabi…
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