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Synthesis and properties of ferrocenylalkyl derivatives of indazole
Authors:Gumenyuk  V. V.  Starikova  Z. A.  Nekrasov  Yu. S.  Babin  V. N.
Affiliation:(1) Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991 Moscow, Russian Federation
Abstract:Ferrocenylmethylation and agr-ferrocenylethylation of indazole were carried out for the first time. Both reactions afforded two isomers, which were characterized by physical and physicochemical methods, among them by X-ray diffraction analysis. 1-(agr-Ferrocenylethyl)indazole is thermally more stable than the 2-substituted isomer. Both isomers serve as ferrocenylalkylating agents with respect to s-triazole.
Keywords:ferrocenylalkylation  indazole  isomers  X-ray diffraction analysis
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