Synthesis and properties of ferrocenylalkyl derivatives of indazole |
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Authors: | Gumenyuk V. V. Starikova Z. A. Nekrasov Yu. S. Babin V. N. |
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Affiliation: | (1) Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
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Abstract: | Ferrocenylmethylation and -ferrocenylethylation of indazole were carried out for the first time. Both reactions afforded two isomers, which were characterized by physical and physicochemical methods, among them by X-ray diffraction analysis. 1-(-Ferrocenylethyl)indazole is thermally more stable than the 2-substituted isomer. Both isomers serve as ferrocenylalkylating agents with respect to s-triazole. |
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Keywords: | ferrocenylalkylation indazole isomers X-ray diffraction analysis |
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