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Germaborenes: Borylene Transfer Agents for the Synthesis of Iminoboranes |
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| Authors: | Dominik Raiser Dr. Hartmut Schubert Prof. Dr. Holger F. Bettinger Prof. Dr. Lars Wesemann |
| Affiliation: | 1. Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany;2. Institut für Organische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany |
| Abstract: | Halide and phenyl substituted germaborenes were shown to react with azides at room temperature and transfer a borylene moiety to give iminoboranes. This iminoborane synthesis based on a borylene transfer route was investigated computationally in the case of the phenyl substituted germaborene. |
| Keywords: | borylene transfer agent germaborenes iminoboranes main group chemistry |