Regioselective Synthesis of 4-Aryl-1,3-dihydroxy-2-naphthoates through 1,2-Aryl-Migrative Ring Rearrangement Reaction and their Photoluminescence Properties |
| |
| Authors: | Dr. Hikaru Yanai Teru Kawazoe Nobuyuki Ishii Prof. Dr. Bernhard Witulski Prof. Dr. Takashi Matsumoto |
| |
| Affiliation: | 1. School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo, 192-0392 Japan;2. Laboratoire de Chimie Moléculaire et Thio-organique, CNRS UMR 6507, ENSICAEN & UNICaen, Normandie Univ., 6 Bvd Maréchal Juin, Caen, 14050 France |
| |
| Abstract: | 4-Aryl-1,3-dihydroxy-2-naphthoates having the less accessible 1,2,3,4-tetrasubstituted naphthalene scaffold and that show photoluminescence emission from solid state as well as in solutions, were selectively synthesized from brominated lactol silyl ethers through the 1,2-aryl-migrative ring rearrangement reaction. |
| |
| Keywords: | Domino reactions Fluorescence Polycycles Rearrangement Synthetic methods |
|
|
