Preparation and Properties of Benzylsulfonyl-Containing Silicone Copolymers via Ring-opening Copolymerization of Macroheterocyclosiloxane and Cyclosiloxane |
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Authors: | Mengdong Guo Yue Huang Zhongkai Chen Yangping Zhang Ya Zhang Mingquan Zhu Prof Jie Zhang Prof Shengyu Feng |
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Institution: | Key Laboratory of Special Functional Aggregated Materials & Key Laboratory of Colloid and Interface Chemistry (Shandong University), Ministry of Education Department, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250199 P. R. China |
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Abstract: | Ring-opening copolymerization (ROCP) of benzylsulfonyl macroheterocyclosiloxane (BSM) and five different cyclosiloxanes was systematically investigated. A general approach for the synthesis of benzylsulfonyl-containing silicone copolymers with various substituents, including methyl, vinyl, ethyl, and phenyl, was developed herein. A series of copolymers with variable incorporation (from 6 % to 82 %) of BSM were obtained by modifying the comonomer feed ratio and using KOH as the catalyst in a mixed solvent of dimethylformamide and toluene. The obtained copolymers exhibited various composition-dependent properties and unique viscoelasticity. Notably, the surface and fluorescent characteristics as well as the glass transition temperatures of the copolymers could be tailored by varying the amount of BSM. Unlike typical sulfone-containing polymers, such as poly(olefin sulfone)s, the prepared copolymers displayed excellent thermal and hydrolytic stability. The universal strategy developed in the present study provides a platform for the design of innovative silicone copolymers with adjustable structures and performance. |
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Keywords: | composition-dependent properties macrocycles polysiloxanes rapid remolding ring-opening copolymerization |
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