Efficient Imine Formation by Oxidative Coupling at Low Temperature Catalyzed by High-Surface-Area Mesoporous CeO2 with Exceptional Redox Property |
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Authors: | Shipeng Wu Yinghao Wang Prof. Qiue Cao Prof. Qihua Zhao Dr. Wenhao Fang |
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Affiliation: | 1. School of Chemical Science and Technology, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Functional Molecules Analysis and Biotransformation, Key Laboratory of Universities in Yunnan Province, Yunnan University, 2 North Cuihu Road, 650091 Kunming, P. R. China;2. School of Chemical Science and Technology, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Functional Molecules Analysis and Biotransformation, Key Laboratory of Universities in Yunnan Province, Yunnan University, 2 North Cuihu Road, 650091 Kunming, P. R. China National Demonstration Center for Experimental Chemistry and, Chemical Engineering Education, Yunnan University, 650091 Kunming, P. R. China |
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Abstract: | High-surface-area mesoporous CeO2 (hsmCeO2) was prepared by a facile organic-template-induced homogeneous precipitation process and showed excellent catalytic activity in imine synthesis in the absence of base from primary alcohols and amines in air atmosphere at low temperature. For comparison, ordinary CeO2 and hsmCeO2 after different thermal treatments were also investigated. XRD, N2 physisorption, UV-Raman, H2 temperature-programmed reduction, O2 temperature-programmed desorption, EPR spectroscopy, and X-ray photoelectron spectroscopy were used to unravel the structural and redox properties. The hsmCeO2 calcined at 400 °C shows the highest specific surface area (158 m2 g−1), the highest fraction of surface coordinatively unsaturated Ce3+ ions (18.2 %), and the highest concentration of reactive oxygen vacancies (2.4×1015 spins g−1). In the model reaction of oxidative coupling of benzyl alcohol and aniline, such an exceptional redox property of the hsmCeO2 catalyst can boost benzylideneaniline formation (2.75 and 5.55 mmol h−1 based on >99 % yield at 60 and 80 °C, respectively) in air with no base additives. It can also work effectively at a temperature of 30 °C and in gram-scale synthesis. These are among the best results for all benchmark ceria catalysts in the literature. Moreover, the hsmCeO2 catalyst shows a wide scope towards primary alcohols and amines with good to excellent yield of imines. The influence of reaction parameters, the reusability of the catalyst, and the reaction mechanism were investigated. |
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Keywords: | imines mesoporous materials oxidative coupling synthetic methods template synthesis |
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