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Emerging Organometallic Methods for the Synthesis of C-Branched (Hetero)aryl,Alkenyl, and Alkyl Glycosides: C?H Functionalization and Dual Photoredox Approaches |
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| Authors: | Juba Ghouilem Morgane de Robichon Dr Franck Le Bideau Dr Angélique Ferry Dr Samir Messaoudi |
| Institution: | 1. Université Paris-Saclay, BioCIS, Faculté de Pharmacie, CNRS, 92290 Châtenay-Malabry, France;2. CY Cergy-Paris Université, BioCIS, Equipe de Chimie Biologique, CNRS, 95000 Neuville sur Oise, France
These authors contributed equally to this work.;3. CY Cergy-Paris Université, BioCIS, Equipe de Chimie Biologique, CNRS, 95000 Neuville sur Oise, France |
| Abstract: | Transition-metal-catalyzed C?H functionalization and photoredox nickel dual catalysis have emerged as innovative and powerful avenues for the synthesis of C-branched glycosides. These two concepts have been recently established and provide efficient and mild methods for accessing a series of valuable complex C-branched glycosides of great interest. Herein, recent developments in the synthesis of C-branched aryl/alkenyl/alkyl glycosides through these two approaches are highlighted. |
| Keywords: | C?H functionalization glycosylation homogeneous catalysis photochemistry transition metals |