Indium Tribromide-Catalysed Transfer-Hydrogenation: Expanding the Scope of the Hydrogenation and of the Regiodivergent DH or HD Addition to Alkenes |
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Authors: | Luomo Li Prof Dr Gerhard Hilt |
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Institution: | Institut für Chemie, Oldenburg University, Carl-von-Ossietzky-Str. 9–11, 26111 Oldenburg, Germany |
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Abstract: | The transfer-hydrogenation as well as the regioselective and regiodivergent addition of H−D from regiospecific deuterated dihydroaromatic compounds to a variety of 1,1-di- and trisubstituted alkenes was realised with InBr3 in dichloro(m)ethane. In comparison with the previously reported BF3⋅Et2O-catalysed process, electron-deficient aryl-substituents can be applied reliably and thereby several restrictions could be lifted, and new types of substrates could be transformed successfully in hydrodeuterogenation as well as deuterohydrogenation transfer-hydrogenation reactions. |
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Keywords: | alkenes catalysis indium tribromide regioselectivity transfer-hydrogenation |
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