Palladium-catalysed dimerisation-distannylation of arynes: synthesis and reaction of 2,2'-distannylbiaryls |
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| Authors: | Yoshida Hiroto Tanino Kenji Ohshita Joji Kunai Atsutaka |
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| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527, Japan. yhiroto@hiroshima-u.ac.jp |
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| Abstract: | Two molar amounts of arynes were found to insert into a Sn-Sn bond of a distannane in the presence of a sub-stoichiometric amount of a palladium-phosphite complex, affording straightforwardly 2,2'-distannylbiaryls. |
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