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On/off electrochemical switches based on quinone-bisketals |
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| Authors: | Fuentes Noelia Álvarez de Cienfuegos Luis Parra Andrés Choquesillo-Lazarte Duane García-Ruiz Juan M Marcos M Luisa Buñuel Elena Ribagorda Maria Carreño M Carmen Cárdenas Diego J Cuerva Juan M |
| Institution: | Departamento de Química Orgánica, Universidad de Granada, Campus Fuentenueva s/n, E-18071 Granada, Spain. |
| Abstract: | The synthesis and anodic oxidation of a variety of 2,5-diaryl or dialkynylaryl substituted 1,4-dialkoxybenzenes to quinone bisketals is described. The study of the X-ray structures and electrochemical and spectroscopic properties evidenced that these pairs constitute a first approach to the concept of a molecular nanofuse. |
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