Metal-free synthesis of substituted phenols from arylboronic acids in water at room temperature |
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| Authors: | Min Jiang, Hai-Jun Yang, Yong Li, Zhi-Ying Jia, Hua Fu |
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| Affiliation: | a Beijing Key Laboratory for Analytical Methods and Instrumentation, Department of Chemistry, Tsinghua University, Beijing 100084, China;b Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China |
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| Abstract: | A convenient,efficient and practical metal-free method for the synthesis of substituted phenols from arylboronic acids has been developed.The protocol uses hydrogen peroxide as a hydroxylating agent ammonium bicarbonate as an additive,and the reactions were conveniently performed in water at room temperature.The method shows an excellent tolerance of functional groups,so it will find a wide variety of applications in academic and industrial research. |
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| Keywords: | Arylboronic acids Substituted phenols Oxidative Metal-free Synthetic method |
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