| Synthesis,Structure and Reactivity of Lanthanocene Complexes |
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| 引用本文： | 钱长涛 朱成建. Synthesis,Structure and Reactivity of Lanthanocene Complexes[J]. 中国化学, 2002, 20(6): 519-535. DOI: 10.1002/cjoc.20020200602 |
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| 作者姓名： | 钱长涛 朱成建 |
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| 作者单位： | [1]StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032,China [2]DepartmentofChemistry,NanjingUniversity,Nanjing210093,Ch |
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| 基金项目： | theNationalNaturalScienceFoundationofChina (Nos.2 9872 0 5 42 9932 0 2 02 0 0 72 0 5 1)，ChineseAcademyofSciences，theMajorStateBasicResearchDevelopmentProgram (No .G2 0 0 0 0 4 80 0 7) |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｃｈｅｍｉｓｔｒｙｏｆｏｒｇａｎｏｌａｎｔｈａｎｉｄｅｓｈａｓｅｘｐｅｒｉｅｎｃｅｄｅｘｔｒｅｍｅｌｙｉｍｐｏｒｔａｎｔｄｅｖｅｌｏｐｍｅｎｔｓｄｕｒｉｎｇｔｈｅｌａｓｔｔｗｏｄｅｃａｄｅｓ ,ａｎｄｎｕｍｅｒｏｕｓｕｎｕｓｕａｌｃｏｍｐｏｕｎｄｓｗｉｔｈｕｎｐｒｅｃｅ ｄｅｎｔｅｄｓｔｒｕｃｔｕｒｅｓａｎｄｕｎｉｑｕｅｒｅａｃｔｉｖｉｔｙｐａｔｔｅｒｎｓｈａｖｅｂｅｅｎｐｒｅｐａｒｅｄ .1ＯｒｇａｎｏｌａｎｔｈａｎｉｄｅｃｏｍｐｏｕｎｄｓｃｏｎｔａｉｎｉｎｇＬｎ—Ｃ ,…
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| 关 键 词： | 镧系配合物 合成 结构 反应性 聚合 X射线衍射 |
Synthesis, Structure and Reactivity of Lanthanocene Complexes |
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| QIAN,Chang Tao ZHU,Cheng Jian a State Key Laboratory of Organometallic Chemistry. Synthesis, Structure and Reactivity of Lanthanocene Complexes[J]. Chinese Journal of Chemistry, 2002, 20(6): 519-535. DOI: 10.1002/cjoc.20020200602 |
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| Authors: | QIAN Chang Tao ZHU Cheng Jian a State Key Laboratory of Organometallic Chemistry |
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| Affiliation: | QIAN,Chang Tao ZHU,Cheng Jian a State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China b Department of Chemistry,Nanjing University,Nanjing 2100 |
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| Abstract: | A variety of lanthanocene complexes, e.g. chlorides, hydrocarbyls, amides, hydrides and divalent derivatives, were synthesized by using a series of designed cyclopentadienyl, indenyl and fluorenyl ligands with ring bridges or dornor functionalized sidearms. X Ray crystallographic analyses reveal the formation of intramolecular coordination bonds between central metals and heteroatoms (O, N) in sidearms or bridging chains. Some applications of these complexes are also discussed in this account. |
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| Keywords: | lanthanocene complex crystal structure cyclopentadienyl ligand indenyl ligand bridging ligand reduction polymerization |
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