Organic vapor triggered repeatable on-off crystalline-state luminescence switching |
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| Authors: | Naka Kensuke Kato Takuji Watase Seiji Matsukawa Kimihiro |
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| Affiliation: | Department of Chemistry and Materials Technology, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-8585, Japan. naka@chem.kit.ac.jp |
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| Abstract: | A nonporous crystalline solid consisting of an organoarsenic platinum(II) complex, i.e., a mononuclear diiodoplatinum(II) complex trans-PtI(2)(cis-DHDAtBu)(2) (1) with cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine (cis-DHDAtBu), shows on-off solid-state luminescence switching through reversible solvent vapor uptake and escape. The on-off switching of solid-state luminescence was achieved without changing the structure or electronic state of the organoarsenic platinum(II) complex. |
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