Dimers of delocalized Ru3O clusters linked by ortho-metallated 2,2'-bipyrimidine in mu4-eta1(C),eta1(C),eta2(N,N),eta2(N,N) mode |
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| Authors: | Ye Heng-Yun Zhang Li-Yi Chen Jing-Lin Chen Zhong-Ning |
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| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. czn@ms.fjirsm.ac.cn. |
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| Abstract: | A remarkable cluster-cluster interaction is operative in dimers of delocalized Ru3O(OAc)5(py)2 clusters with ortho-metallated 2,2'-bipyrimidine (bpym) in an unprecedented mu4-eta1(C),eta1(C),eta2(N,N),eta2(N,N) bonding mode; interconversion of the dimeric species [{Ru3O(OAc)5(py)2}2(micro4-bpym)]n+ (n = 0, 1 or 2) with different charges is attainable by chemical oxidation or reduction. |
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