| Abstract: | The bulk polycondensation of L ‐aspartic acid (ASP) with an acid catalyst under batch and continuous conditions was established as a preparative method for producing poly(succinimide) (PSI). Although sulfuric acid, p‐toluenesulfonic acid, and methanesulfonic acid were effective at producing PSI in a high conversion of ASP, o‐phosphoric acid was the most suitable catalyst for yielding PSI with a high weight‐average molecular weight (Mw) in a quantitative conversion; that is, the Mw value was 24,000. For the continuous process using a twin‐screw extruder at 3.0 kg · h?1 of the ASP feed rate, the conversion was greater than 99%, and the Mw value was 23,000 for the polycondensation with 10 wt % o‐phosphoric acid at 260°C. Sodium polyaspartate (PASP‐Na) originating from the acid‐catalyzed polycondensation exhibited high biodegradability and calcium‐ion‐chelating ability. The total organic carbon value was 86 ～ 88%, and 100 g of PASP‐Na chelated with 5.5 ～ 5.6 g of calcium ion, which was similar to the value for PASP‐Na from the acid‐catalyzed polycondensation with a mixed solvent © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 117–122, 2000 |
