Two‐electron atomic systems confined within spheroidal boxes |
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Authors: | A. Corella‐Madueñ o,R. A. Rosas,J. L. Marí n,R. Riera |
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Abstract: | The direct variational method is used to estimate some interesting physical properties of the He atom and the Li+ ion confined within impenetrable spheroidal boxes. A comparative investigation of the ground‐state energy, pressure, polarizability, dipole, and quadrupole moments with those of the He atom inside boxes with paraboloidal walls is made. The overall results show a similar qualitative behavior. However, for Li+ there are quantitative differences on such properties due to its major nuclear charge, as expected. The trial wave function is constructed as a product of two hydrogenic wave functions adapted to the geometry of the confining boxes. © 2000 John Wiley & Sons, Inc. Int J Quant Chem 77: 509–515, 2000 |
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Keywords: | model of atoms trapped inside solids electronic structure helium atom pressure, polarizability, dipole, and quadrupole moments of trapped atoms |
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