The creation and spatial structure of end-linked bimodal polymer networks: a Monte Carlo study |
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| Affiliation: | 1. School of Chemical and Biological Engineering, Seoul National University, Seoul 08826, Republic of Korea;2. Institute of Chemical Process, Seoul National University, Seoul 08826, Republic of Korea |
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| Abstract: | The creation and spatial structure of end-linked bimodal polymer networks was investigated by means of the three-dimensional bond-fluctuation model. The portion of long and short chains was varied. The curing process was found to be reaction-controlled within our simulation parameters. The spatial distribution of the cross-linkers in the created networks revealed no large-scale inhomogeneities. Investigations of the pair-correlation functions of the center of mass of the short chains were consistent with the random distribution of the cross-linkers. |
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