Die Kristallstruktur der hydratisierten Cyanokomplexe NMe4MnII[(Mn, Cr)III(CN)6] · 3 H2O und NMe4Cd[MIII(CN)6] · 3 H2O (MIII = Fe,Co): Verwandte des Berliner Blaus |
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Authors: | M Witzel B Ziegler D Babel |
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Abstract: | The Crystal Structure of the Hydrated Cyano Complexes NMe4MnII(Mn, Cr)III(CN)6] · 3 H2O and NMe4CdMIII(CN)6] · 3 H2O (MIII = Fe, Co): Compounds Related to Prussian Blue The crystal structures of the isotypic tetragonal compounds (space group I4, Z = 10) NMe4MnII · (Mn, Cr)III(CN)6] · 3 H2O (a = 1653.2(4), c = 1728.8(6) pm), NMe4CdFe(CN)6] · 3 H2O (a = 1642.7(1), c = 1733.1(1) pm) and NMe4CdCo(CN)6] · 3 H2O (a = 1632.1(2), c = 1722.4(3) pm) were determined by X‐rays. They exhibit ⊥ c cyanobridged layers of octahedra MIII(CN)6] and MIIN4(OH2)2], which punctually are interconnected also || c to yield altogether a spaceous framework. The MII atoms at the positions linking into the third dimension are only five‐coordinated and form square pyramids MIIN5] with angles N–MII–N near 104° and distances of Mn–N: 1 × 214, 4 × 219 pm; Cd–N: 1 × 220 resp. 222, 4 × 226 resp. 228 pm. Further details and structural relations within the family of Prussian Blue are reported and discussed. |
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Keywords: | Crystal structure Hexacyanometallates(III) Prussian Blue |
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