Functional microporous materials of metal carboxylate: Gas-occlusion properties and catalytic activities |
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Authors: | Wasuke Mori Tomohiko Sato Tesushi Ohmura Chika Nozaki Kato Tohru Takei |
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Institution: | Department of Chemistry, Faculty of Science, Kanagawa University, Hiratsuka, Kanagawa 259-1293, Japan |
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Abstract: | Copper(II) terephthalate is the first transition metal complex found capable of adsorbing gases. This complex has opened the new field of adsorbent complex chemistry. It is recognized as the lead complex in the construction of microporous complexes. This specific system has been expanded to a systematic series of derivatives of other isomorphous transition metals, molybdenum(II), ruthenium(II, III), and rhodium(II). These complexes with open frameworks are widely recognized as very useful materials for applications to catalysis, separation at molecular level, and gas storage. |
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Keywords: | Gas-occlusion properties Transition metal carboxylate polymer complex Self-assembly Metalloporphyrin Microporous material Olefin hydrogenation Hydrogen exchange reactions |
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