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高温高压气体状态方程研究及钱学森方程改进
引用本文:赵波,崔季平,樊菁. 高温高压气体状态方程研究及钱学森方程改进[J]. 力学学报, 2010, 42(2): 151-158. DOI: 10.6052/0459-1879-2010-2-2009-029
作者姓名:赵波  崔季平  樊菁
作者单位:中国科学院力学研究所高温气体动力学重点实验室中国科学院力学研究所高温气体动力学重点实验室中国科学院力学研究所高温气体动力学重点实验室
摘    要:钱学森根据分子动理论的普遍原则,结合Lennard-JonesDevanshire(LJD)液体理论的结果,给出了一个适用于高温高压气体的普适状态方程. 该方程有物理基础,且具有计算精度高、形式简单及显含温度的优点. 本文用分子动力学方法检验了LJD理论的适用性,并给出精确的高温高压气体状态方程分子动力学数值解, 在此基础上修订了钱学森状态方程. 改进后的钱学森状态方程在高密度范围内与MD结果平均绝对偏差率小于10%. 

关 键 词:高温高压气体   钱学森状态方程   分子动力学   Lennard-Jones势
收稿时间:2009-01-15
修稿时间:2009-06-07

AN IMPROVEMENT OF TSIEN'S EQUATION OF STATE IN HIGH-TEMPERATURE AND HIGH-PRESSURE GASES
Zhao Bo , Cui Jiping , Fan Jing. AN IMPROVEMENT OF TSIEN'S EQUATION OF STATE IN HIGH-TEMPERATURE AND HIGH-PRESSURE GASES[J]. chinese journal of theoretical and applied mechanics, 2010, 42(2): 151-158. DOI: 10.6052/0459-1879-2010-2-2009-029
Authors:Zhao Bo    Cui Jiping    Fan Jing
Affiliation:Key Laboratory of High Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, ChinaInstitute of Mechanics, Chinese Academy of Sciences, Beijing 100190, ChinaKey Laboratory of High Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China
Abstract:According to the general principle of molecular dynamics theory and the Lennard-Jones Devonshire (LJD) liquid theory,H.S.Tsien given an fundamental equation of state for gases at high temperatures and pressures.Tsien's EOS has physical foundation,high accuracy eqlicit temperature,and simple form.In this paper,we tested the applicability of LJD liquid theory in high-temperature and high-pressure gases by constant volume-temperature molecular dynamics,and obtained exact MD calculations for high temperature an...
Keywords:high-temperature and high-pressure gases  Tsien's equation of state  molecular dynamics  Lennard-Jones potential  
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