| 规整链球型含C_(60)聚(丙烯酸β-羟乙酯)的合成及其在水中的自组装 |
| |
| 引用本文： | 黎淳昭,张炜程,魏柳荷,杜福胜,李子臣,李福绵. 规整链球型含C_(60)聚(丙烯酸β-羟乙酯)的合成及其在水中的自组装[J]. 高分子学报, 2002, 0(1): 120-122 |
| |
| 作者姓名： | 黎淳昭 张炜程 魏柳荷 杜福胜 李子臣 李福绵 |
| |
| 作者单位： | 北京大学化学与分子工程学院高分子科学与工程系,北京,100871 |
| |
| 基金项目： | 国家自然科学基金资助项目(基金号29992590-4) |
| |
| 摘 要： | Ｃ60 由于其独特的物理化学性质 ,在生命科学中引起了人们的广泛兴趣 .例如 :水溶性Ｃ60 的羧酸衍生物 ,羟基取代Ｃ60 ,Ｃ60 的氨基酸水溶性衍生的合成已有报道[1～ 3] ,并被用来研究Ｃ60 的生物化学及医学活性 .Ｔｏｋｕｙａｍａ[4 ] 等合成了酶功能化Ｃ60及与核酸连接的Ｃ60 ,研究并证明了它的细胞毒性及Ｇ 选择ＤＮＡ切割能力等生化活性 .Ｆｒｉｅｄｍａｎ[5]等合成了水溶性Ｃ60 的羧酸衍生物 ,研究了它对ＨＩＶ 1艾滋病毒的抑制作用 ,此外 ,关于不同Ｃ60含量的Ｃ60 蛋白质衍生物的合成及性质的研究也有报道[6] .Ｃ60 是一个直径为 0 71…
|
| 关 键 词： | 原子转移自由基聚合 链球型含C60聚合物 囊泡 透射电镜 荧光 |
| 修稿时间： | 2001-07-30 |
SYNTHESIS OF A WELL-DEFINED HAMMER-LIKE C60 CONJUGATED POLY(2-HYDROXYETHYL ACRYLATE) AND ITS SELF-ASSEMBLY IN WATER |
| |
| LI Chunzhao,ZHANG Weicheng,WEI Liuhe,DU Fusheng,LI Zichen,LI Fumian. SYNTHESIS OF A WELL-DEFINED HAMMER-LIKE C60 CONJUGATED POLY(2-HYDROXYETHYL ACRYLATE) AND ITS SELF-ASSEMBLY IN WATER[J]. Acta Polymerica Sinica, 2002, 0(1): 120-122 |
| |
| Authors: | LI Chunzhao ZHANG Weicheng WEI Liuhe DU Fusheng LI Zichen LI Fumian |
| |
| Abstract: | Atom transfer radical polymerization of protected 2 hydroxyethyl acrylate (HEA|TMS) was conducted to prepare well|defined bromo|terminated macroinitiators,which were further allowed to react with large excess amount of C 60 under ATRP condition.A well defined hammer shaped C 60 PHEA was then obtained by hydrolysis of C 60 PHEA TMS under mild conditions.A TEM observation of the association behavior of these well defined hammer like C 60 PHEA macromolecules showed that they assemble into spherical vesicles in water.Their characteristic inner water phase was further confirmed by fluorescence probe method.Also,it was found that the size of vesicles decreased as the increase of molecular weight of PHEA. |
| |
| Keywords: | Atom transfer radical polymerization Hammer shaped C 60 conjugated polyhydroxyethyl acrylate Vesicle Transmission electron microscopy Fluorescence probe |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
