| 钼络合物催化的丙炔醇和丙炔氯共聚反应研究 |
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| 引用本文： | 白明章,孙丽娟,沙耀武,余祥.钼络合物催化的丙炔醇和丙炔氯共聚反应研究[J].高分子学报,1985,0(1):73-76. |
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| 作者姓名： | 白明章 孙丽娟 沙耀武 余祥 |
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| 作者单位： | 南开大学元素有机化学研究所
(白明章，孙丽娟，沙耀武)，南开大学元素有机化学研究所(余祥) |
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| 摘 要： | <正> 乙炔或取代乙炔的聚合反应已有很多研究,其聚合物是一种很有希望的有机导体和半导体材料。但两种取代乙炔的共聚反应研究却不多。前文报道了单一的丙炔醇或丙炔氯等取代乙炔和钼的含硫配位体络合物生成加合物,并不发生聚合。后来发现丙炔醇和丙炔氯的混合物在上述钼络合物存在下发生共聚反应。
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| 收稿时间： | 1983-12-16 |
STUDY ON MOLYBDENUM COMPLEXES CATALYZED COPO-LYMERIZATION OF PROPARGYL ALCOHOL AND PROPARGYL CHLORIDE |
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| Bai Ming-zhang,Sun Li-juan,Sa Yao-wu,Yu Xiang.STUDY ON MOLYBDENUM COMPLEXES CATALYZED COPO-LYMERIZATION OF PROPARGYL ALCOHOL AND PROPARGYL CHLORIDE[J].Acta Polymerica Sinica,1985,0(1):73-76. |
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| Authors: | Bai Ming-zhang Sun Li-juan Sa Yao-wu Yu Xiang |
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| Institution: | Institute of Elemento-Organic Chemistry; Nankai University |
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| Abstract: | The Polymerization of acetylenes have been extensively studied, for the polymers obtained are a kind of prospective material of organic conductor and semiconductor.We Found that in the presence of molybdenum complexes, propargyl alcohol and propargyl chloride copolymerized with vigorous reactions. We obtained polymer Ⅰ insoluble in all solvents studied, and polymer Ⅱ, solubel in methanol, chloroform, acetone etc., with molecular weight 700-1000.We have tried using 9 complexes of Ti, Zr, Fe, Co, Ni as catalyst, but no reaction has taken place. |
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