Tetraphenylbismuth 2,4-Dimethylbenzenesulfonate: Synthesis and Structure |
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| Authors: | Sharutin V V Egorova I V Ivanenko T K Sharutina O K Pavlushkina I I Gerasimenko A V |
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| Institution: | (1) Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia;(2) Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 109, Vladivostok, 690022, Russia |
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| Abstract: | Tetraphenylbismuth 2,4-dimethylbenzenesulfonate was synthesized by reacting pentaphenylbismuth or bromine with diphenylbismuth 2,4-dimethylbenzenesulfonate and its structure was established using X-ray diffraction analysis. The Bi atom has a distorted trigonal bipyramidal coordination. The Bi–C bond lengths are equal to 2.199(4)–2.227(4) Å the Bi–O distance and axial CBiO angle are equal to 2.665(3) Å and 174.2(1)°, respectively. |
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