Synthesis,Structure, and Physicochemical Properties of Lithium Uranovanadate |
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| Authors: | Suleimanov E. V. Chernorukov N. G. Karyakin N. V. Knyazev A. V. |
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| Affiliation: | (1) Lobachevskii Nizhny Novgorod State University, Nizhny Novgorod, Russia |
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| Abstract: | A new chemical compound, lithium uranovanadate, was synthesized and studied by X-ray diffraction, IR spectroscopy, and thermography. Standard enthalpies of formation of lithium uranovanadate and its dihydrate at 298.15 K were determined by means of reaction and adiabatic vacuum calorimetry. Temperature dependence of heat capacity in the range 80-300 K was obtained for crystalline LiVUO6·2H2O and thermodynamic characteristics of its synthesis were calculated. |
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